按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。


1. 第一(yi)類氫(qing)脆


 氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。


 上(shang)述三種情(qing)況將造成金屬永久(jiu)損(sun)傷,使材料塑性(xing)或強度降低,即使從金屬中除(chu)氫損(sun)傷也不能(neng)消除(chu),塑性(xing)或強度也不能(neng)恢復,故稱為不可逆氫脆。


2. 第(di)二類氫脆


 氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)的(de)(de)(de)敏感性(xing)(xing)隨應(ying)(ying)變(bian)(bian)(bian)(bian)速(su)(su)率增(zeng)加(jia)(jia)而降低,即材(cai)料在(zai)加(jia)(jia)載前(qian)并(bing)不(bu)存在(zai)裂(lie)(lie)紋源,加(jia)(jia)載后(hou)在(zai)應(ying)(ying)力和氫(qing)(qing)(qing)(qing)(qing)(qing)的(de)(de)(de)交(jiao)(jiao)互(hu)(hu)作用(yong)下逐漸形(xing)(xing)成(cheng)裂(lie)(lie)紋源,最終(zhong)導致脆(cui)(cui)(cui)性(xing)(xing)斷裂(lie)(lie)。第(di)二類氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)包(bao)括兩(liang)種(zhong)形(xing)(xing)式:一是(shi)應(ying)(ying)力誘發氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)(hua)物(wu)(wu)(wu)(wu)型(xing)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)。在(zai)能夠形(xing)(xing)成(cheng)脆(cui)(cui)(cui)性(xing)(xing)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)(hua)物(wu)(wu)(wu)(wu)的(de)(de)(de)金屬中(zhong)(zhong),當氫(qing)(qing)(qing)(qing)(qing)(qing)含(han)量較低或(huo)氫(qing)(qing)(qing)(qing)(qing)(qing)在(zai)固溶體中(zhong)(zhong)的(de)(de)(de)過飽和度較低時,尚不(bu)能自(zi)發形(xing)(xing)成(cheng)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)(hua)物(wu)(wu)(wu)(wu);而在(zai)應(ying)(ying)力作用(yong)下,氫(qing)(qing)(qing)(qing)(qing)(qing)會向應(ying)(ying)力集(ji)(ji)中(zhong)(zhong)處富集(ji)(ji),當氫(qing)(qing)(qing)(qing)(qing)(qing)濃度超過臨界值時就會沉淀出(chu)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)(hua)物(wu)(wu)(wu)(wu)。這種(zhong)應(ying)(ying)力誘發的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)(hua)物(wu)(wu)(wu)(wu)相變(bian)(bian)(bian)(bian)只在(zai)較低的(de)(de)(de)應(ying)(ying)變(bian)(bian)(bian)(bian)速(su)(su)率下出(chu)現,并(bing)由此導致脆(cui)(cui)(cui)性(xing)(xing)斷裂(lie)(lie),一旦出(chu)現氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)(hua)物(wu)(wu)(wu)(wu),即使卸載除氫(qing)(qing)(qing)(qing)(qing)(qing),靜(jing)止一段(duan)時間(jian)(jian)后(hou)再高速(su)(su)變(bian)(bian)(bian)(bian)形(xing)(xing),塑(su)性(xing)(xing)也不(bu)能恢(hui)復,故也是(shi)不(bu)可(ke)(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)。二是(shi)可(ke)(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)。是(shi)指含(han)氫(qing)(qing)(qing)(qing)(qing)(qing)金屬在(zai)高速(su)(su)變(bian)(bian)(bian)(bian)形(xing)(xing)時并(bing)不(bu)顯示脆(cui)(cui)(cui)性(xing)(xing),而在(zai)緩慢變(bian)(bian)(bian)(bian)形(xing)(xing)時由于氫(qing)(qing)(qing)(qing)(qing)(qing)逐漸向應(ying)(ying)力集(ji)(ji)中(zhong)(zhong)處富集(ji)(ji),在(zai)應(ying)(ying)力與(yu)氫(qing)(qing)(qing)(qing)(qing)(qing)交(jiao)(jiao)互(hu)(hu)作用(yong)下裂(lie)(lie)紋形(xing)(xing)核、擴展,最終(zhong)導致脆(cui)(cui)(cui)性(xing)(xing)的(de)(de)(de)斷裂(lie)(lie),在(zai)未形(xing)(xing)成(cheng)裂(lie)(lie)紋前(qian)去除載荷(he),靜(jing)置一段(duan)時間(jian)(jian)后(hou)高速(su)(su)變(bian)(bian)(bian)(bian)形(xing)(xing),材(cai)料的(de)(de)(de)塑(su)性(xing)(xing)可(ke)(ke)以得(de)到恢(hui)復,即應(ying)(ying)力去除后(hou)脆(cui)(cui)(cui)性(xing)(xing)消失,因此稱(cheng)(cheng)為可(ke)(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)。由內(nei)氫(qing)(qing)(qing)(qing)(qing)(qing)引(yin)(yin)起的(de)(de)(de)稱(cheng)(cheng)可(ke)(ke)逆(ni)(ni)內(nei)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui),由外氫(qing)(qing)(qing)(qing)(qing)(qing)引(yin)(yin)起的(de)(de)(de)稱(cheng)(cheng)環境氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)。通常(chang)所說的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)主(zhu)要指可(ke)(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui),是(shi)氫(qing)(qing)(qing)(qing)(qing)(qing)致開裂(lie)(lie)中(zhong)(zhong)最主(zhu)要、最危(wei)險的(de)(de)(de)破壞形(xing)(xing)式。