不銹鋼的爐(lu)中(zhong)釬焊(han)一般是在(zai)某種保(bao)護性氣(qi)(qi)氛(fen)下或真(zhen)空中(zhong)進行,保(bao)護氣(qi)(qi)氛(fen)有氫氣(qi)(qi)、分解氨和(he)氬(ya)氣(qi)(qi)。
干燥的氫氣或分解氨常用做爐中釬焊不銹鋼時的還原性保護氣氛,它們可還原不銹(xiu)鋼表面的氧化膜,并保護不銹鋼表面在釬焊時不再氧化。一般要求氫氣或分解氨的露點低于-40℃,但也要考慮保護氣體的露點要與釬焊溫度及母材的成分相適應。釬焊溫度越低、不銹鋼表面氧化膜越穩定,要求氫氣露點越低,見圖3-4。使用分解氨作保護氣氛時,必須保證NH3完全分解,避免殘余的NH3使不銹鋼表面氮化。

使(shi)用氫(qing)氣(qi)(qi)或(huo)(huo)分解氨(an)作保護氣(qi)(qi)氛的好(hao)處(chu)是:可實(shi)現(xian)釬(han)(han)焊爐的連續工作,便于(yu)大批量生(sheng)產(chan)(chan);釬(han)(han)焊過程中(zhong)不需使(shi)用釬(han)(han)劑,且焊后工件光亮,無(wu)需任何焊后工件表面清理工作;可配合選用的釬(han)(han)料品種多;在批量生(sheng)產(chan)(chan)條件下焊接成本(ben)低。但是使(shi)用氫(qing)氣(qi)(qi)或(huo)(huo)分解氨(an)作保護氣(qi)(qi)氛時(shi)要注意生(sheng)產(chan)(chan)安全(quan),當空氣(qi)(qi)中(zhong)混有4%~74%的氫(qing)氣(qi)(qi)或(huo)(huo)12.5%~27%氨(an)氣(qi)(qi)時(shi),會因燃燒而產(chan)(chan)生(sheng)爆(bao)炸。
作為(wei)惰(duo)性(xing)氣(qi)體,氬(ya)氣(qi)可(ke)用作爐中(zhong)釬焊(han)不銹鋼時的(de)保護(hu)(hu)氣(qi)氛。與氫氣(qi)和分解氨不同(tong),氬(ya)氣(qi)不具有還原性(xing),只是(shi)利用其(qi)惰(duo)性(xing)保護(hu)(hu)不銹鋼表面(mian)在(zai)釬焊(han)過程(cheng)中(zhong)不氧(yang)化,所以不銹鋼進爐釬焊(han)前(qian)必(bi)須徹底清(qing)除其(qi)表面(mian)的(de)氧(yang)化膜,并(bing)且一般要求氬(ya)氣(qi)的(de)露點低于-40℃。
使(shi)用(yong)氬氣作保護氣氛一般(ban)是因為以下某種(zhong)或多種(zhong)原因:①. 可采用(yong)含高蒸汽壓元(yuan)素(su)的(de)釬,如錳基釬料或含錳較(jiao)多的(de)釬料;②. 單件(jian)或小批量釬焊(han)時(shi),設備成(cheng)本低(di);③. 不(bu)銹(xiu)(xiu)鋼(gang)與(yu)(yu)(yu)異種(zhong)材釬焊(han)時(shi)避免某些材料與(yu)(yu)(yu)爐內氣氛的(de)反應(ying)(ying),如在(zai)含氫(qing)(qing)氣氛中釬焊(han)連接不(bu)銹(xiu)(xiu)鋼(gang)與(yu)(yu)(yu)鈦合金時(shi),鈦金吸氫(qing)(qing)并與(yu)(yu)(yu)氫(qing)(qing)反應(ying)(ying);④. 生產(chan)過程安全。
使用氬氣作保護氣氛時,常見的做法是將真空爐抽至高真空后(10-2~10-3Pa)充入少量氬氣,關閉爐體氣閥后升溫。或者在特制的密封容器內通人流動的氬氣,將空氣趕凈后,容器放入馬弗爐內加熱。也可在趕凈空氣后,關閉氣路,容器放人馬弗爐內加熱,但在升溫過
程中要(yao)隨時(shi)注意容器(qi)內(nei)(nei)的(de)(de)壓(ya)力,當容器(qi)內(nei)(nei)壓(ya)力超(chao)過(guo)大氣(qi)(qi)壓(ya)較多時(shi)應隨時(shi)放出一(yi)些(xie)氣(qi)(qi)體(ti),以保(bao)證容器(qi)完(wan)好(hao)和生產安全。使(shi)用(yong)特(te)制的(de)(de)容器(qi)還(huan)有另一(yi)個便利(li):當使(shi)用(yong)未經凈化的(de)(de)普(pu)通(tong)瓶裝氬氣(qi)(qi)時(shi),可向釬焊爐內(nei)(nei)通(tong)入少許BF3氣(qi)(qi)體(ti)釬劑,或加入少許氟硼酸(suan)鉀,氟硼酸(suan)鉀在(zai)800~900℃分(fen)(fen)解(jie)產生BF3.BF3可以去除金(jin)屬表面的(de)(de)氧(yang)化物(wu),促(cu)進釬料的(de)(de)潤濕。氣(qi)(qi)體(ti)釬劑的(de)(de)使(shi)用(yong)濃(nong)度一(yi)般(ban)控制在(zai)0.1%~0.001%(體(ti)積分(fen)(fen)數),避免(mian)焊后形(xing)成(cheng)殘渣(zha)。氟化物(wu)對人體(ti)有害,要(yao)注意工作場地的(de)(de)通(tong)風。
在真空爐中釬焊不銹鋼是一種常用且理想的方法。釬焊不銹鋼時一般要求真空度達到10-2~10-3Pa,并且要求真空爐的氣體泄漏率小于10-2Pa/s.使用真空爐釬焊不銹鋼的好處是:可避免不銹鋼的氧化;可避免釬焊爐內氣氛對母材的不良影響;真空爐升、降溫速度慢,工件不變形或變形量很小;無論以何種方式添加釬料均不會在接頭內形成氣孔;無需消耗保護氣體;無需氣體凈化裝置;無安全隱患;帶有充氣及快冷風扇置的真空爐同樣具有較高的生產率,并可實現釬焊與焊后工件熱處理的結合。
在氫氣或分解氨氣氛爐中釬焊不銹鋼可使用紫銅、銅基、銀基、錳基、鎳基和金基釬料。在氬氣氛爐中釬焊不銹鋼可使用銅基、銀基、錳基、金基釬料。在真空爐中釬焊不銹鋼可采用紫銅、不含易蒸發元素(Zn、Cd)或僅含少量高蒸汽壓元素(Mn)的銅基和銀基釬料、鎳基釬料和金基釬料。使用鎳基釬料釬焊不銹鋼薄件時,要選擇對母材溶蝕傾向小的釬料。
爐中釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)時(shi)(shi)影響釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)接(jie)頭性能,特別是力學性能的(de)(de)主(zhu)要工(gong)藝(yi)參(can)數(shu)包釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)、保溫(wen)(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)。釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)一般(ban)選擇(ze)在(zai)(zai)釬(han)(han)(han)(han)(han)(han)料(liao)液相線(xian)溫(wen)(wen)(wen)(wen)度(du)(du)以(yi)上50~100℃,保溫(wen)(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)在(zai)(zai)5~10min.當(dang)工(gong)件(jian)較大(da)時(shi)(shi),可在(zai)(zai)升溫(wen)(wen)(wen)(wen)過(guo)程中釬(han)(han)(han)(han)(han)(han)料(liao)固相線(xian)溫(wen)(wen)(wen)(wen)度(du)(du)以(yi)下某(mou)溫(wen)(wen)(wen)(wen)度(du)(du)保溫(wen)(wen)(wen)(wen)一段時(shi)(shi)間(jian)(jian)(jian),確保工(gong)件(jian)溫(wen)(wen)(wen)(wen)度(du)(du)均勻(yun)。使(shi)用鎳(nie)基(ji)(ji)釬(han)(han)(han)(han)(han)(han)料(liao)時(shi)(shi),除了釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)和(he)(he)保溫(wen)(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)外,釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)(jian)隙(xi)(xi)也是接(jie)頭強(qiang)(qiang)度(du)(du)和(he)(he)塑(su)(su)性的(de)(de)決定(ding)(ding)因素之一。圖3-5、圖3-6顯示了三(san)種(zhong)鎳(nie)基(ji)(ji)釬(han)(han)(han)(han)(han)(han)料(liao)釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)不銹鋼時(shi)(shi)釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)接(jie)頭強(qiang)(qiang)度(du)(du)與(yu)釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)(jian)隙(xi)(xi)的(de)(de)關系。為降(jiang)低釬(han)(han)(han)(han)(han)(han)料(liao)的(de)(de)熔點,鎳(nie)基(ji)(ji)釬(han)(han)(han)(han)(han)(han)料(liao)中含有較多的(de)(de)硼、硅(gui)(gui)、磷(lin)(lin),它(ta)們在(zai)(zai)釬(han)(han)(han)(han)(han)(han)料(liao)組(zu)織中以(yi)脆性的(de)(de)硼化(hua)物、硅(gui)(gui)化(hua)物、磷(lin)(lin)化(hua)物形(xing)式存在(zai)(zai)。釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)時(shi)(shi)在(zai)(zai)一定(ding)(ding)的(de)(de)釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)和(he)(he)保溫(wen)(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)下,當(dang)釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)(jian)隙(xi)(xi)小于某(mou)一數(shu)值,硼、硅(gui)(gui)、磷(lin)(lin)向母(mu)材擴(kuo)散充分,凝固后釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)組(zu)織為鎳(nie)基(ji)(ji)固溶體,釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)強(qiang)(qiang)度(du)(du)高、塑(su)(su)性好,此數(shu)值稱作該釬(han)(han)(han)(han)(han)(han)料(liao)在(zai)(zai)此釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)和(he)(he)保溫(wen)(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)下的(de)(de)最(zui)大(da)釬(han)(han)(han)(han)(han)(han)焊(han)(han)(han)間(jian)(jian)(jian)隙(xi)(xi)。當(dang)釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)(jian)隙(xi)(xi)超過(guo)最(zui)大(da)間(jian)(jian)(jian)隙(xi)(xi),釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)中硼、硅(gui)(gui)、磷(lin)(lin)向母(mu)材擴(kuo)散不充分,釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)中會存在(zai)(zai)脆性化(hua)合物,釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)的(de)(de)強(qiang)(qiang)度(du)(du)和(he)(he)塑(su)(su)性都(dou)會下降(jiang)。而(er)且(qie)在(zai)(zai)一定(ding)(ding)范圍內,釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)越(yue)寬,釬(han)(han)(han)(han)(han)(han)縫(feng)(feng)中脆性相越(yue)多,接(jie)頭的(de)(de)強(qiang)(qiang)度(du)(du)和(he)(he)塑(su)(su)性越(yue)低。

在釬焊(han)(han)實(shi)際部件(jian)時,有時部件(jian)加(jia)工精(jing)度或(huo)裝配精(jing)度很難保(bao)(bao)證(zheng)釬縫(feng)間(jian)隙很小,適當(dang)地提(ti)高釬焊(han)(han)溫(wen)度或(huo)延(yan)長(chang)保(bao)(bao)溫(wen)時間(jian)可增(zeng)大最大釬焊(han)(han)間(jian)隙,見圖(tu)3-7。當(dang)在高溫(wen)下長(chang)時間(jian)保(bao)(bao)溫(wen)造成母(mu)材晶粒(li)過分長(chang)大或(huo)釬料對(dui)母(mu)材溶蝕(shi)過度時,也可在焊(han)(han)后接頭冷卻到(dao)某一較低(di)溫(wen)度保(bao)(bao)溫(wen),通過擴散(san)消(xiao)除(chu)釬縫(feng)中的脆性相而(er)增(zeng)大最大釬焊(han)(han)間(jian)隙,見圖(tu)3-8。但由于磷原子較大,向母(mu)材中擴散(san)困(kun)難,這些措施對(dui)Ni-Cr-P和Ni-P這類釬料作用不大。

爐中釬焊時為控制釬料不流到接頭外其他部位或造成工件與卡具的粘連,可在防止釬料潤濕處涂止焊劑。釬焊不銹鋼時可以用TiO2、Y2O3或云母粉與乙醇混和后做止焊劑。

